aside from polished alloys, if your wheels are painted in either single or two stage (base coat clear coat) the best is to use a paint coating such as cquartz, opticoat, etc. you'll want to remove the wheels and do the barrels also.
if you don't want to go through the trouble above any easy on/off paint sealant will typically work as well. re-apply every so often so sealant is always on there.
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